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The Clue

Gunpowder ingredient (9 letter answer)

The Answer

SALTPETER

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Notes

The answer SALTPETER is so rare that it appears less than once every 2500 puzzles.

Definition

SALTPETER as a noun:

1. (potassium nitrate, saltpeter, saltpetre, niter, nitre) = (KNO3) used especially as a fertilizer and explosive